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RoHS elemental screening

XRF screening considerations and instrument configurations for electrical and electronic materials.

Application context

Electrical and electronic products contain plastics, metals, ceramics, glass, solvents and chemicals. Target substances and sampling methods should be selected according to the product, components, customer requirements and controlled materials.

The original site describes the early six-substance RoHS framework: lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls (PBB) and polybrominated diphenyl ethers (PBDE). It records the EU implementation date of 1 July 2006 and a 0.1% lead limit. Its statement that China RoHS “will be implemented in the second half of 2012” is historical. These statements are not a current regulatory checklist or a compliance determination.

Materials and locations identified on the original site

Substance Examples in the original material
Lead (Pb) Solder, glass, PVC stabilizers
Mercury (Hg) Thermostats, sensors, switches, relays, lamps
Cadmium (Cd) Switches, springs, connectors, housings, PCBs, contacts, batteries
Hexavalent chromium Anti-corrosion coatings on metals
PBB and PBDE Flame retardants in PCBs, connectors and plastic housings

Product examples include refrigerators, washing machines, microwave ovens, air conditioners, vacuum cleaners and water heaters; audio/video, IT, digital and telecommunications products; power tools, electronic toys and medical electrical equipment. Regulatory scope must be checked for the product and target market.

Testing approach

Complex electronic components may not be suitable for complete grinding and homogeneous sampling. Selecting sampling locations and methods is therefore important for useful analytical results. Internal corporate environmental specifications may also cover additional substances.

The original site records Nayur's cooperation with the Ministry of Industry and Information Technology's technical promotion center for pollution control in electrical and electronic products, offering XRF instruments and application solutions for production material control.

XRF provides elemental screening. Total chromium and total bromine results do not directly identify hexavalent chromium or specific brominated flame retardants; appropriate confirmation methods may be required. Testing items, limits and decision rules must follow the applicable requirements.

Instruments recommended on the original site

Model Composite filters Minimum spot diameter Mapping Published positioning
NaU1000 12 1 mm Optional manual Mapping General RoHS screening
NDA200 16 0.5 mm Optional manual Mapping Complex samples without disassembly
NDA300 16 0.5 mm Optional automatic Mapping Laboratories and testing organizations; electrically cooled SDD detector, identified as US-made on the original site

NaU1000 NDA200 for testing without disassembly NDA300 for testing without disassembly

Configurations are taken from the original site. Confirm suitability for actual samples and the currently supplied configuration.

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